Structural Elucidation of Sumanene and Generation of Its Benzylic Anions
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- Hidehiro Sakurai
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
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- Taro Daiko
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
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- Hiroyuki Sakane
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
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- Toru Amaya
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
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- Toshikazu Hirao
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
書誌事項
- 公開日
- 2005-07-28
- DOI
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- 10.1021/ja0518169
- 公開者
- American Chemical Society (ACS)
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説明
The structure of sumanene in a solid state was elucidated. The silyl-substituted sumanene was stereoselectively synthesized through generation of the benzylic anions of sumanene.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 127 (33), 11580-11581, 2005-07-28
American Chemical Society (ACS)