AMMONO method of BN, AlN and GaN synthesis and crystal growth.

書誌事項

公開日
1998
権利情報
  • https://www.cambridge.org/core/terms
DOI
  • 10.1557/s1092578300000971
公開者
Springer Science and Business Media LLC

説明

<jats:p>Microcrystals of BN, AlN and GaN were obtained by the AMMONO method, in which nitridization of metal occurs in supercritical ammonia, at relatively low temperature and pressure conditions (below 550°C and 5 kbar). The reaction rate was regulated by the amount of mineralizers, i.e. alkali metal amides.</jats:p><jats:p>All crystals obtained by AMMONO method revealed intense and homogenous luminescence. Significant improvement of the optical properties was observed for crystals grown in the presence of Rare Earth elements. For such GaN crystals, helium temperature photoluminescence spectra were dominated by near-band-gap recombination. Exciton lines were extremely narrow, with full-width half-maximum (FWHM) as low as 1 meV. The concentration of uncompensated shallow donors in AMMONO GaN determined by electron paramagnetic resonance measurements was below 5×10<jats:sup>15</jats:sup> cm<jats:sup>−3</jats:sup>.</jats:p>

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