Chiral Guanidine Catalyzed Acylative Kinetic Resolution of Racemic 2-Bromo-1-arylethanols

DOI PDF 被引用文献2件 参考文献46件
  • Erika Sawada
    Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, Shimane 690-8504 , Japan
  • Kenya Nakata
    Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, Shimane 690-8504 , Japan

書誌事項

公開日
2020-11-27
資源種別
journal article
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.200786
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>In this study, chiral guanidine catalyzed acylative kinetic resolution of racemic 2-bromo-1-arylethanols was achieved with high selectivity. Irrespective of the electronic nature and the substitution patterns on the aromatic rings, a variety of substrates were suitable for this reaction. The branched acyl component was considered to be optimal for obtaining high s-values. The transition state of the reaction was proposed based on the absolute configuration of the obtained product.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 50 (2), 371-373, 2020-11-27

    Oxford University Press (OUP)

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