Efficient Catalytic Plasma Activation of CO<sub>2</sub>, NO, and H<sub>2</sub>O

DOI Web Site 被引用文献9件
  • Steven L. Suib
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan
  • Stephanie L. Brock
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan
  • Manuel Marquez
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan
  • Jian Luo
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan
  • Hiroshige Matsumoto
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan
  • Yuji Hayashi
    Department of Chemistry, U-60, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Chemical Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-4060, Department of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06511, Department of Chemistry, Nagasaki University, Bunkyomachi 1-14 Nagasaki 852, Japan, and Fujitsu Laboratories, Ltd., 1015 Kamikodanaka, Nakahara 211, Japan

書誌事項

公開日
1998-11-01
DOI
  • 10.1021/jp9822079
公開者
American Chemical Society (ACS)

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説明

The activation of small molecules, such as CO2, NO, and H2O, has been achieved at atmospheric pressure via ac glow discharge methods in the presence of metal catalysts coated onto the electrode surfaces. A fan-type reactor having one rotating and one static electrode has been designed to diminish mass transfer effects. Time lapse photography of the emitting plasma intermediate species and optical emission studies have been used to monitor reaction pathways. Gas chromatography, mass spectrometry, and combined GC−MS methods have been used to monitor product distributions, selectivities, and activities. The effects of flow rate, input voltage, diluent gases, and metal coating have been systematically studied. Additionally, the mechanisms of CO2 decomposition and the role of the metal catalyst in that decomposition have been studied by optical emission spectroscopy.

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