Methoxy‐ and Aminoisocyanate

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<jats:title>Abstract</jats:title><jats:p>Methoxyisocyanate (<jats:bold>1</jats:bold>) can be prepared by photolysis of methyl azidoformate (<jats:bold>3</jats:bold>) or pyrolysis of <jats:italic>N</jats:italic>‐methoxycarbonyl‐<jats:italic>O</jats:italic>‐methyl‐hydroxylamine (<jats:bold>4</jats:bold>). Aminoisocyanate (<jats:bold>2</jats:bold>) is similarly formed on photolysis of carbamoyl azide (<jats:bold>12</jats:bold>) and pyrolysis of either methyl carbazate (<jats:bold>13</jats:bold>) or 3,4‐diaminofurazan (<jats:bold>14</jats:bold>). The infrared spectra of <jats:bold>1</jats:bold> and <jats:bold>2</jats:bold> in an argon matrix at 10 K have been measured, and some of their properties are discussed.</jats:p>

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