The atom, the molecule, and the covalent organic framework

  • Christian S. Diercks
    Department of Chemistry, University of California, Berkeley, CA 94720, USA; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA; Kavli Energy NanoSciences Institute, Berkeley, CA 94720, USA; Berkeley Global Science Institute, Berkeley, CA 94720, USA; and King Abdulaziz City for Science and Technology, Riyadh 11442, Saudi Arabia.
  • Omar M. Yaghi
    Department of Chemistry, University of California, Berkeley, CA 94720, USA; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA; Kavli Energy NanoSciences Institute, Berkeley, CA 94720, USA; Berkeley Global Science Institute, Berkeley, CA 94720, USA; and King Abdulaziz City for Science and Technology, Riyadh 11442, Saudi Arabia.

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<jats:title>A framework for molecular assembly</jats:title> <jats:p>Covalent molecular frameworks are crystalline microporous materials assembled from organic molecules through strong covalent bonds in a process termed reticular synthesis. Diercks and Yaghi review developments in this area, noting the parallels between framework assembly and the covalent assembly of atoms into molecules, as described just over a century ago by Lewis. Emerging challenges include functionalization of existing frameworks and the creation of flexible materials through the design of woven structures.</jats:p> <jats:p> <jats:italic>Science</jats:italic> , this issue p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6328" page="eaal1585" related-article-type="in-this-issue" vol="355" xlink:href="10.1126/science.aal1585">eaal1585</jats:related-article> </jats:p>

収録刊行物

  • Science

    Science 355 (6328), eaal1585-, 2017-03-03

    American Association for the Advancement of Science (AAAS)

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