Highly Efficient Hydrogen Storage System Based on Ammonium Bicarbonate/Formate Redox Equilibrium over Palladium Nanocatalysts

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<jats:title>Abstract</jats:title><jats:p>A highly efficient, reversible hydrogen storage–evolution process has been developed based on the ammonium bicarbonate/formate redox equilibrium over the same carbon‐supported palladium nanocatalyst. This heterogeneously catalyzed hydrogen storage system is comparable to the counterpart homogeneous systems and has shown fast reaction kinetics of both the hydrogenation of ammonium bicarbonate and the dehydrogenation of ammonium formate under mild operating conditions. By adjusting temperature and pressure, the extent of hydrogen storage and evolution can be well controlled in the same catalytic system. Moreover, the hydrogen storage system based on aqueous‐phase ammonium formate is advantageous owing to its high volumetric energy density.</jats:p>

Journal

  • ChemSusChem

    ChemSusChem 8 (5), 813-816, 2015-02-06

    Wiley

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