Hydrogenation of carbon dioxide and carbon monoxide over supported rhodium catalysts under 10 bar pressure
書誌事項
- 公開日
- 1989-01
- 権利情報
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- https://www.elsevier.com/tdm/userlicense/1.0/
- DOI
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- 10.1016/s0166-9834(00)81390-1
- 公開者
- Elsevier BV
この論文をさがす
説明
Abstract The hydrogenation of carbon dioxide and carbon monoxide was carried out in a 10-atm flow reactor over supported rhodium catalysts. Rh/ZrO 2 and Rh/Nb 2 O 5 showed the highest activity for carbon dioxide and hydrogenation, the main product being methane. Methanol was formed selectively from carbon dioxide hydrogen over a Rh/TiO 2 catalyst. The products of carbon monoxide hydrogenation over supported Rh catalysts contained higher hydrocarbons and ethanol. The rate of C -C bond formation was higher in carbon monoxide hydrogenation than in carbon dioxide hydrogenation. The effect of the support on hydrogenation of carbon dioxide and carbon monoxide is discussed.
収録刊行物
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- Applied Catalysis
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Applied Catalysis 46 (1), 1-9, 1989-01
Elsevier BV