Highly Enantioselective Alkynylation of Trifluoropyruvate with Alkynylsilanes Catalyzed by the BINAP−Pd Complex: Access to α-Trifluoromethyl-Substituted Tertiary Alcohols
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- Kohsuke Aikawa
- Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan
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- Yu̅ta Hioki
- Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan
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- Koichi Mikami
- Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan
書誌事項
- 公開日
- 2010-11-16
- DOI
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- 10.1021/ol102541s
- 10.1002/chin.201113051
- 公開者
- American Chemical Society (ACS)
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説明
<jats:title>Abstract</jats:title><jats:p>The process is highly successful including the addition of polyynes such as (VI) and (VIII) to trifluoropyruvate (II).</jats:p>
収録刊行物
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- Organic Letters
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Organic Letters 12 (24), 5716-5719, 2010-11-16
American Chemical Society (ACS)