Effect of Si on liquid Fe compressibility: Implications for sound velocity in core materials

  • C. Sanloup
    Laboratoire MAGIE Universitã Paris‐6 Paris France
  • G. Fiquet
    Laboratoire de Minéralogie‐Cristallographie Université Paris‐6 Paris France
  • E. Gregoryanz
    Laboratoire de Minéralogie‐Cristallographie Université Paris‐6 Paris France
  • G. Morard
    Laboratoire de Minéralogie‐Cristallographie Université Paris‐6 Paris France
  • M. Mezouar
    Experiments Division European Synchrotron Radiation Facility Grenoble France

書誌事項

公開日
2004-04
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1029/2004gl019526
公開者
American Geophysical Union (AGU)

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説明

<jats:p>Density of liquid Fe‐Si alloys was measured in situ up to 5 GPa‐1725 K by an X‐ray absorption technique using synchrotron radiation. Increasing the amount of silicon in liquid iron decreases the bulk incompressibility by only −0.5 GPa per 1 weight% of Si. These data confirm our previous prediction of a negligible effect of Si on liquid Fe bulk properties, prediction based on the observation of a similar local structure in liquid Fe and liquid Fe‐Si alloys. Si and S have therefore opposite effects on P‐waves velocity (<jats:italic>v</jats:italic><jats:sub><jats:italic>P</jats:italic></jats:sub> = <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/grl18089-math-0001.gif" xlink:title="equation image"/>), both elements reduce the bulk density of liquid iron but only S affects its compressibility. Since compression‐wave velocities in the Earth's outer core are slightly higher than in pure liquid Fe in the same P‐T conditions, it implies that Si would correct this discrepancy while S would increase it.</jats:p>

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