Synergistic adsorption behavior of a silica-based adsorbent toward palladium, molybdenum, and zirconium from simulated high-level liquid waste
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説明
In this study, the synergistic adsorption behavior of palladium [Pd(II)], molybdenum [Mo(VI)], and zirconium [Zr(IV)] in simulated high-level liquid waste was systematically investigated based on various factors, such as the contact time, concentration of nitric acid, adsorption amount, and temperature using a silica-based adsorbent impregnated with N,N'-dimethyl-N,N'-di-n-hexyl-thiodiglycolamide (Crea) and 2, 2', 2' -nitrilotris[N,N-bis(2-ethylhexyl)acetamide] (TAMIA-EH). The adsorption rates of Pd(II), Mo(VI), and Zr(IV) in this synergistic adsorption system were high; thus, equilibrium states could be obtained in only 1 h with high uptake percentages of more than 90%. The adsorption abilities of Pd(II), Mo(VI), and Zr(IV) were only slightly affected by variation in the concentration of nitric acid in the range of 0.1-5 M and solution temperature in the range of 288-313 K. Selective stripping of the adsorbed Re(VII), Pd(II), Zr(IV), and Mo(VI) was successfully achieved under elution with 5 M HNO
収録刊行物
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- Journal of Hazardous Materials
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Journal of Hazardous Materials 411 125136-, 2021-06
Elsevier BV
