Electronic structures of organic/organic heterojunctions: From vacuum level alignment to Fermi level pinning

  • J. X. Tang
    City University of Hong Kong Center Of Super-Diamond and Advanced Films (COSDAF), , Hong Kong SAR, China and Department of Physics and Materials Science, , Hong Kong SAR, China
  • C. S. Lee
    City University of Hong Kong Center Of Super-Diamond and Advanced Films (COSDAF), , Hong Kong SAR, China and Department of Physics and Materials Science, , Hong Kong SAR, China
  • S. T. Lee
    City University of Hong Kong Center Of Super-Diamond and Advanced Films (COSDAF), , Hong Kong SAR, China and Department of Physics and Materials Science, , Hong Kong SAR, China

書誌事項

公開日
2007-03-15
DOI
  • 10.1063/1.2710297
公開者
AIP Publishing

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説明

<jats:p>Electronic structures of organic/organic (O/O) heterojunctions have been studied by photoemission spectroscopy. We showed that vacuum level alignment is only valid for certain O/O heterojunctions rather than a general rule for organic junctions. The mode of energy level alignment is found to depend on the Fermi level position in the organic energy gap. In general, when the Fermi level is near the midgap position, vacuum level alignment at the O/O heterojunction is observed, whereas when the Fermi level is close to the edge of the lowest unoccupied or highest occupied molecular orbital level, Fermi level pinning accompanied by molecular orbital level bending is observed at the O/O heterojunction.</jats:p>

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