Thermal equation of state and thermodynamic Grüneisen parameter of beryllium metal

  • Jianzhong Zhang
    Los Alamos Neutron Science Center, Los Alamos National Laboratory 1 , Los Alamos, New Mexico 87545, USA
  • Jinlong Zhu
    Los Alamos Neutron Science Center, Los Alamos National Laboratory 1 , Los Alamos, New Mexico 87545, USA
  • Nenad Velisavljevic
    Dynamic & Energetic Materials Division, Los Alamos National Laboratory 2 , Los Alamos, New Mexico 87545, USA
  • Liping Wang
    High Pressure Science and Engineering Center and Department of Physics and Astronomy, University of Nevada 3 , Las Vegas, Nevada 89154, USA
  • Yusheng Zhao
    High Pressure Science and Engineering Center and Department of Physics and Astronomy, University of Nevada 3 , Las Vegas, Nevada 89154, USA

書誌事項

公開日
2013-11-05
DOI
  • 10.1063/1.4828886
公開者
AIP Publishing

この論文をさがす

説明

<jats:p>We conducted in-situ high-pressure synchrotron x-ray experiments on beryllium metal at pressures up to 7.9 GPa and temperatures up to 1373 K. A complete pressure (P)–volume (V)–temperature (T) equation of state (EOS) is determined based on the experiment, which includes temperature derivatives of elastic bulk modulus (at both constant pressure and constant volume) and pressure dependence of thermal expansivity. From this EOS, we calculate thermal pressure, heat capacity at constant volume, and thermodynamic Grüneisen parameter as a function of temperature. Above ∼600 K, our results show notable deviation from theoretical predictions using the quasiharmonic and local-density approximations, indicating that the free energy calculations need to be further improved within the current scheme of approximations.</jats:p>

収録刊行物

被引用文献 (1)*注記

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ