Microstructure and tacticity in radical copolymerization I.

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<jats:title>Abstract</jats:title><jats:p>The NMR spectra of styrene‐methyl methacrylate copolymers were found to exhibit a multiplicity in the 2.0–3.6δ region characteristic for methoxy protons. The methoxy pattern is explained by taking into account the degree of shielding of methoxy protons, in relation to both number and configuration of the neighbouring styrene units along the chain. The relative areas of the methoxy peaks are compared with results of the statistical analysis of monomer sequence probabilities.</jats:p>

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