書誌事項
- 公開日
- 1988-10
- 権利情報
-
- https://www.elsevier.com/tdm/userlicense/1.0/
- DOI
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- 10.1016/0016-2361(88)90137-8
- 公開者
- Elsevier BV
この論文をさがす
説明
Abstract The thermal decomposition of the diarylmethane in hydrogen-donor solvents proceeds via the ipso-addition of a hydrogen atom transferred from the solvent. This reaction is slow in tetralin at temperatures of 430–460 °C, but it is promoted by a binary solvent system composed of tetralin and dibenzyl (20:1 molar ratio), and its ability to donate hydrogen is comparable with that of 9,10-dihydroanthracene. The additive effect of 1H-phenalene as a source of phenalenyl radical is half that of dibenzyl. The addition of a hydrogen shuttler such as anthracene and phenanthrene to tetralin also promotes the above reaction, but their additive effect is modest, compared with the hydrogen-donating abilities of the corresponding dihydro-derivatives.
収録刊行物
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- Fuel
-
Fuel 67 (10), 1436-1440, 1988-10
Elsevier BV
