Effect of Mutual Configuration between Molecular Orientation and Atomic Orientation in the Oriented Ar<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mo stretchy="false">(</mml:mo><mml:mmultiscripts><mml:mi>P</mml:mi><mml:mn>2</mml:mn><mml:none/><mml:mprescripts/><mml:none/><mml:mn>3</mml:mn></mml:mmultiscripts><mml:mo stretchy="false">)</mml:mo><mml:mo>+</mml:mo><mml:mtext mathvariant="normal">Oriented</mml:mtext></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>CF</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mi mathvariant="normal">H</mml:mi></mml:math>Reaction
書誌事項
- 公開日
- 2007-07-23
- 権利情報
-
- http://link.aps.org/licenses/aps-default-license
- DOI
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- 10.1103/physrevlett.99.043201
- 公開者
- American Physical Society (APS)
この論文をさがす
説明
The steric effect in the dissociative energy transfer reaction of Ar (3P2,MJ=2)+CF3H has been observed as a function of the mutual configurations between the molecular orientation and the atomic orientation in the collision frame. The reactivity is significantly changed depending on the mutual configuration between the molecular orientation and the atomic orientation. Especially, the molecular alignment dependence is dramatically changed depending on the configuration of the atomic alignment.
収録刊行物
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- Physical Review Letters
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Physical Review Letters 99 (4), 043201-, 2007-07-23
American Physical Society (APS)
