Polymer‐Based Stimuli‐Responsive Recyclable Catalytic Systems for Organic Synthesis

書誌事項

公開日
2013-07-15
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/smll.201300287
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>The introduction of stimuli‐responsive polymers into the study of organic catalysis leads to the generation of a new kind of polymer‐based stimuli‐responsive recyclable catalytic system. Owing to their reversible switching properties in response to external stimuli, these systems are capable of improving the mass transports of reactants/products in aqueous solution, modulating the chemical reaction rates, and switching the catalytic process on and off. Furthermore, their stimuli‐responsive properties facilitate the separation and recovery of the active catalysts from the reaction mixtures. As a fascinating approach of the controllable catalysis, these stimuli‐responsive catalytic systems including thermoresponsive, pH‐responsive, chemo‐mechano‐chemical, ionic strength‐responsive, and dual‐responsive, are reviewed in terms of their nanoreactors and mechanisms.</jats:p>

収録刊行物

  • Small

    Small 10 (1), 32-46, 2013-07-15

    Wiley

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