Formation of a Pt<sub>12</sub> Cluster by Single‐Atom Control That Leads to Enhanced Reactivity: Hydrogenation of Unreactive Olefins
書誌事項
- 公開日
- 2013-05-31
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ange.201302860
- 10.1002/anie.201302860
- 公開者
- Wiley
この論文をさがす
説明
A platinum subnanocluster catalyst composed of 12 atoms was synthesized using a phenylazomethine dendrimer, which can assemble twelve PtCl4 units by stepwise complexation, followed by reduction to Pt(0). Unreactive olefins that were not activated by conventional 2 nm Pt nanoparticles were successfully hydrogenated by the subnanocluster. EWG = electron-withdrawing group.
収録刊行物
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- Angewandte Chemie
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Angewandte Chemie 125 (29), 7567-7569, 2013-05-31
Wiley