Domain Pinning: Comparison of Hafnia and PZT Based Ferroelectrics

  • Franz P. G. Fengler
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany
  • Milan Pešić
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany
  • Sergej Starschich
    Institut für Werkstoffe der Elektrotechnik 2 RWTH Aachen Sommerfeldstr. 24 D‐52074 Aachen Germany
  • Theodor Schneller
    Institut für Werkstoffe der Elektrotechnik 2 RWTH Aachen Sommerfeldstr. 24 D‐52074 Aachen Germany
  • Christopher Künneth
    Department of Applied Sciences and Mechatronics Munich University of Applied Sciences Lothstr. 34 D‐80335 München Germany
  • Ulrich Böttger
    Institut für Werkstoffe der Elektrotechnik 2 RWTH Aachen Sommerfeldstr. 24 D‐52074 Aachen Germany
  • Halid Mulaosmanovic
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany
  • Tony Schenk
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany
  • Min Hyuk Park
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany
  • Robin Nigon
    Laboratoire de Céramique EPFL, MX‐D Ecublens 1015 Lausanne Switzerland
  • Paul Muralt
    Laboratoire de Céramique EPFL, MX‐D Ecublens 1015 Lausanne Switzerland
  • Thomas Mikolajick
    Chair of Nanoelectronic Materials TU Dresden D‐01062 Dresden Germany
  • Uwe Schroeder
    NaMLab gGmbH Noethnitzer Str. 64 Dresden D‐01187 Germany

書誌事項

公開日
2017-03-08
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/aelm.201600505
公開者
Wiley

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説明

<jats:p>Even though many studies on the field cycling behavior of ferroelectric hafnium oxide have recently been published, the issue is still not fully understood. The initial increase of polarization during first cycles is explained by different theoretical and empirical approaches. Field‐induced phase changes as well as oxygen vacancy diffusion from interfacial layers toward the bulk are discussed. Trapped charges as well as the mentioned oxygen vacancy diffusion might cause a shift of the hysteresis along the voltage axis called imprint. Even though various studies connect this effect to charge diffusion with progression of cycling, a final experimental proof for the origin of wake‐up and imprint is still missing. Based on the comprehensive comparative study of hafnia–zirconia and iron‐doped lead zirconate titanate ferroelectrics, it is verified that the diffusion of oxygen vacancies is the main cause for both imprint and wake‐up. Moreover, it is shown that a local seed inhibition of ferroelectric domains is most likely responsible for the reduced ferroelectric response in pristine state.</jats:p>

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