Structural and optical properties of nanocrystalline Zn1−xMnxO

  • K. Samanta
    University of Puerto Rico Department of Physics, , San Juan, Puerto Rico 00931-23343
  • S. Dussan
    University of Puerto Rico Department of Physics, , San Juan, Puerto Rico 00931-23343
  • R. S. Katiyar
    University of Puerto Rico Department of Physics, , San Juan, Puerto Rico 00931-23343
  • P. Bhattacharya
    Fisk University Department of Physics, , Nashville, Tennessee 37209

書誌事項

公開日
2007-06-25
DOI
  • 10.1063/1.2751593
公開者
AIP Publishing

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説明

<jats:p>The multi phonon Raman scattering in Mn doped (1%–10%) ZnO was observed at room temperature using 514.5nm Ar+ laser. The additional optical modes at 327, 332, 482, 532, and 680cm−1 in Zn1−xMnxO targets were identified as the second order Raman modes in the disordered lattice and the precipitation of the secondary phase ZnMn2O4. The crystalline grain sizes of 1%, 3%, 5%, and 10% Mn doped ZnO samples were calculated by phonon confinement model as 31.8, 18.3, 15.9, and 14.1nm, respectively. The optical band gap was found to be increased (3.27–3.41eV) due to the Mn doping.</jats:p>

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