From Simple Chalcogenidotetrelate Precursors to Complex Structures and Functional Compounds

書誌事項

公開日
2012-09-18
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/zaac.201200319
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Chalcogenidotetrelates show a rich and complex chemistry encompassing intricate structures and useful materials. A step‐wise coordination chemistry approach allows the sequential formation of multinary M/T/E anions (M = transition metal, T = tetrel, E = chalcogen) from simple T/E building blocks in solution. This way, a range of compounds displaying different structure types of molecular as well as extended multinary anions were obtained. To allow for even further variety, the approach can be extended to organo‐functionalized chalcogenidotetrelates. Here, the organic shell of the inorganic cages plays a decisive role in reactivity and resulting structures. The formation structures and properties of these compounds will be discussed in detail in this perspective article.</jats:p>

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