Nickel(0)-Catalyzed Dimerization of Ethyl Cyclopropylideneacetates

  • Taishi Kawasaki
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan
  • Shinichi Saito
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan
  • Yoshinori Yamamoto
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan, and Institute for Chemical Reaction Science, Tohoku University, Sendai 980-8578, Japan

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説明

The dimerization of ethyl cyclopropylideneacetates proceeded in the presence of Ni(0) catalysts, and cyclic compounds or linear compounds were formed in selective manners. The structures of products were highly dependent on the structure of the substrate and the ligands bound to the catalyst. The mechanism of the reactions was discussed in detail.

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