Preparation and properties of chiral 4-pyrrolidinopyridine (PPY) analogues with dual functional side chains

書誌事項

公開日
2003-02
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/s0040-4039(03)00021-2
公開者
Elsevier BV

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説明

Abstract Chiral 4-pyrrolidinopyridine analogues 8 – 13 with two distinct functional side chains at C(2) and C(4) of the pyrrolidine ring were prepared from 4-hydroxy- l -proline. We examined desymmetrization of meso -1,3-cyclohexanediol through enantioselective acylation using these catalysts and found that introduction of a C(4)-side chain was effective for improving both the chemo- and enantioselectivity of acylation.

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