Suzuki–Miyaura reactions promoted by a PdCl<sub>2</sub>/sulfonate‐tagged phenanthroline precatalyst in water

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  • Qi Li
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China
  • Li‐Ming Zhang
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China
  • Jia‐Jing Bao
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China
  • Hong‐Xi Li
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China
  • Jing‐Bo Xie
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China
  • Jian‐Ping Lang
    College of Chemistry, Chemical Engineering and Materials Science Soochow University Suzhou 215123 PR China

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<jats:p>This work reports Suzuki–Miyaura cross‐coupling reactions of arylboronic acid with aryl halide or aryl dibromide mediated by PdCl<jats:sub>2</jats:sub> (0.05 mol%) and sodium 4‐(1H‐imidazo[4,5‐f][1,10]phenanthrolin‐1‐yl)butane‐1‐sulfonate (0.05 mol%) at 100 °C in water. The corresponding cross‐coupling products were obtained in good to excellent yields. The catalytic system was recovered from the organic products by extraction with ether and the residual aqueous catalyst phase showed high activity after reuse of at least four cycles. Copyright © 2014 John Wiley & Sons, Ltd.</jats:p>

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