Fluoride Complexation of Element 104, Rutherfordium

  • Hiromitsu Haba
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Kazuaki Tsukada
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Masato Asai
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Atsushi Toyoshima
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Kazuhiko Akiyama
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Ichiro Nishinaka
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Masaru Hirata
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Tsuyoshi Yaita
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Shin-ichi Ichikawa
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Yuichiro Nagame
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Ken-ichiro Yasuda
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Yutaka Miyamoto
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Tetsuya Kaneko
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Shin-ichi Goto
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Sawako Ono
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Toshiyuki Hirai
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Hisaaki Kudo
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Mitsuru Shigekawa
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Atsushi Shinohara
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Yasuji Oura
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Hiromichi Nakahara
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Keisuke Sueki
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Hidetoshi Kikunaga
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Norikazu Kinoshita
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Naoya Tsuruga
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Akihiko Yokoyama
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Minoru Sakama
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Shuich Enomoto
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Matthias Schädel
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Willy Brüchle
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...
  • Jens V. Kratz
    Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty...

説明

Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9-13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

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