Determination of Optimum Woking Conditions for Spectroscopic Detection of Impurites in Ammonium Paratungstate by the Application of Statistical Techniques

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  • 統計的手法を応用したパラタングステン酸アンモニウム中の不純物の分光分析作業条件の決定法
  • トウケイテキ シュホウ オ オウヨウ シタ パラタングステンサン アンモニウム チュウ ノ フジュンブツ ノ ブンコウ ブンセキ サギョウ ジョウケン ノ ケッテイホウ

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To determine optimum working conditions for spectrochemical analysis of the impurities in ammonium pa atungstate by the Carrier-Distillation Method, <BR>(i) the author determined the degree of suppression of tungsten spectrum numerically by the equation, <BR>E=S3/S1+S2<BR>where, S1+S2= intensity of tungsten spectrum lines.<BR>S3=intensity of impurity spectrum lines.<BR>(ii) he then applied the statistical techniques in experiments, i. e., the orthogonal array method in the first experiment, and, randomized block method in the second experiment, taking E as the characteristics.<BR>In spite of the existence of many unknown factors which might affect the results of analysis, the optimum conditions are thus obtained very efficiently.

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