鉄(III)-キシレノールオレンジ錯体の組成および吸光光度定量法への応用

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タイトル別名
  • Composition of the Xylenol Orange complexes of iron (III) and their application to the determination of iron or Xylenol Orange
  • テツ III -キシレノールオレンジ サクタイ ノ ソセイ オヨビ キュウコウ コウド テイリョウホウ エ ノ オウヨウ

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説明

Iron (III) reacts with an excess of Xylenol Orange to form 1:1 and 1:2 complexes with their absorption maxima at 545 and 500 mμ, respectively, while only a 1:1 complex with its absorption maximum at about 586 mμ is formed when an excess of iron is present. The molar extinction coefficients and the apparent formation constants of these complexes were spectrophotometrically determined.<BR>As little as 3μg/25ml of iron was determined successfully with any one complex of the former two, and as little as 0.025μmol/25ml and of Xylenol Orange with the latter. The absorbance in every case conforms well to Beer's law.

収録刊行物

  • 分析化学

    分析化学 14 (8), 677-682, 1965

    公益社団法人 日本分析化学会

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