Sensitive and selective determination of pesticides in air using a high-resolution gas chromatograph/high-resolution mass spectrometer.

DOI NDL Digital Collections Web Site Web Site 19 References
  • MURAYAMA Hitoshi
    Niigata Prefectural Institute of Public Health and Environmental Sciences
  • MUKAI Hiroyuki
    Niigata Prefectural Institute of Public Health and Environmental Sciences
  • TANABE Akiko
    Niigata Prefectural Institute of Public Health and Environmental Sciences
  • MORIYAMA Noboru
    Niigata Prefectural Institute of Public Health and Environmental Sciences
  • KITAYAMA Yoshie
    Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University

Bibliographic Information

Other Title
  • 高分離能ガスクロマトグラフ／高分解能質量分析計を用いる大気中農薬の高感度及び高選択的測定
  • 技術論文 高分離能ガスクロマトグラフ/高分解能質量分析計を用いる大気中農薬の高感度及び高選択的測定
  • ギジュツ ロンブン コウブンリノウ ガス クロマトグラフ コウ ブンカイノウ シツリョウ ブンセキケイ オ モチイル タイキ チュウ ノウヤク ノ コウカンド オヨビ コウセンタクテキ ソクテイ

Search this article

Description

Applications of a high-resolution gas chromatograph/high-resolution mass spectrometer (HRGC/HRMS) have been examined with regard to the precise determination of various kinds of pesticides in air to low concentrations. The results for a comparison of the resolution of mass spectrometry indicated that the signal-noise ratio for pesticides in the standard solution improved for 21 of 28 kinds of pesticides at high resolution (R=5000). In addition, interfering substances readily influence the chromatograms of actual samples, though these substances were excluded from almost all of the pesticides due to improved resolution. This HRGC/HRMS method allowed an actual determination of pesticides in air. The collection of 10 m3 of air was performed with activated carbon tube collection. Following extraction, fractionation was performed with a florisil column. Sensitive and selective determinations to the order of 10-3 μg/m3 proved to be possible with respect to samples concentrated to 1 ml.

Journal

  • BUNSEKI KAGAKU

    BUNSEKI KAGAKU 50 (8), 537-545, 2001

    The Japan Society for Analytical Chemistry

References(19)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top