Syntheses, Structures and Properties of the Cluster Compounds Nb6I11-xBrx and Y2-xMxC2Br2-yIy(M=Sr, La, Lu, Th).
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- YOSHIASA Akira
- Facuity of Science, Osaka University
Bibliographic Information
- Other Title
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- 金属クラスター化合物Ｎｂ６Ｉ１１－ｘＢｒｘおよびＹ２－ｘＭｘＣ２Ｂｒ２－ｙＩｙ（Ｍ＝Ｓｒ，Ｌａ，Ｌｕ，Ｔｈ）の結晶構造と物性
- キンゾク クラスターカゴウブツ Nb6I11-xBrx オヨビ Y2-xMxC
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Abstract
Crystal structure, chemical bonding and physical property are discussed for the metal-rich cluster compound Nb6I11-xBrx containing discrete clusters and the layered cluster compound Y2-xMxC2Br2-yIy, focusing on the effect of replacement by other atoms having different mass, size and bonding. Nb6I11-xBrx undergoes a spin cross-over phase transition and with increasing Br content the transition temperature shifts from 274 to 170 K. The highest superconducting transition temperature in the yttrium ethenide halides occurs at a intermediate composition rather than at each end-member.
Journal
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- Nihon Kessho Gakkaishi
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Nihon Kessho Gakkaishi 38 (2), 167-173, 1996
The Crystallographic Society of Japan
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Details 詳細情報について
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- CRID
- 1390001204085889408
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- NII Article ID
- 10002025069
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- NII Book ID
- AN00188364
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- ISSN
- 18845576
- 03694585
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- NDL BIB ID
- 4002802
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed
