Recent Advance in Structural Studies under Extreme Conditions. X-ray Diffraction Studies of Light-Induced Metastable- and Excited-State Molecular Crystal.

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  • 特殊条件下の構造研究の新展開　　光照射による励起構造，準安定構造
  • ヒカリ ショウシャ ニ ヨル レイキコウゾウ , ジュンアンテイ コウゾウ

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Abstract

Crystallographic studies of metastable and excited state molecular crystals provide direct geometrical information for those of light-induced structure changes or transition states in solid-state chemical reactions. Such geometry changes will give only very small difference in X-ray diffraction intensities. Special instrumentation and data acquisition technique must be required in order to detect small changes of intensity. This review describes a few examples of experimental and analysis technique applying to photo-excited crystallography.

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