コバルト系層状銅酸化物の規則・不規則構造の電顕観察

  • 長井 拓郎
    物質・材料研究機構超高圧電子顕微鏡ステーション
  • 松井 良夫
    物質・材料研究機構超高圧電子顕微鏡ステーション

書誌事項

タイトル別名
  • TEM Observation of Structural Order and Disorder in Co-Based Layered Cuprates
  • サイキン ノ ケンキュウ カラ コバルトケイ ソウジョウ ドウ サンカブツ ノ キソク フキソク コウゾウ ノ デンケンカンサツ

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抄録

Crystal structures of Co-based layered cuprates, CoSr2 (Y, Ce) s8Cu2O5+2s (s=1-3), have been investigated by high-resolution electron microscopy (HREM) and electron diffraction (ED) techniques. For all the phases ED patterns showed double periodicity along a direction parallel to the CoO layers, indicating a regular alternation of two types of CoO4-tetrahedra chains within the layers. Also seen was ordering of the chains along the layer-stacking direction for the s=1 phase. For the other phases the investigation revealed complete disordering of the chains along the layer-stacking direction. This implies that the interlayer ordering is mainly controlled by the distance between the neighboring CoO layers.

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