ポリグリセリン脂肪酸エステルの水-油系での相挙動とキュービック相で安定化された乳化ゲル生成

  • 國枝 博信
    横浜国立大学大学院工学研究科人工環境システム学専攻
  • 荒牧 賢治
    横浜国立大学工学部物質工学科
  • 西村 貴幸
    横浜国立大学大学院工学研究科人工環境システム学専攻
  • 石飛 雅彦
    三菱化学株式会社横浜総合研究所機能化学研究所

書誌事項

タイトル別名
  • Phase Behavior of Polyglycerin Fatty Acid Ester in a Water-Oil System and Formulations of Gel-Emulsions Stabilized by the Cubic Phase
  • ポリグリセリン シボウサン エステル ノ スイ ユケイ デ ノ ソウ キョドウ ト キュービックソウ デ アンテイカ サレタ ニュウカ ゲル セイセイ

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説明

Examination was made of the phase behavior of polyglycerin fatty acid esters in a water-oil system and aggregate structure by phase study and amall angle X-ray scattering (SAXS). Polyglycerin laurate (10G* 0.7L and 20G* 1L) were used, 10G* and 20G* indicating the average polymerization degree of polyglyceryl chain as 10 and 20, respectively. Neither 10G* 0.7L nor 20G* 1L formed a cubic phase in water at 25°C but did so with the addition of a trace amount of decane. The cubic phase was found to be a discontinuous micellar cubic phase (I1) with a face or body centered cubic lattice by SAXS. Micelles in I1 were not completely spherical. The thermal stability of I1 was improved with increase in the solubilization of decane. Maximum solubilization of m-xylene and squalane in I1 was studied and greater solubilization of m-xylene and less solubilization of squalane compared to decane were noted. An excess oil phase was found to coexist with I1 beyond the solubilization limit of I1 and the oil phase could be dispersed in I1 as emulsion droplets. The highly viscous and stable gel emulsion with oil content of 80% could be formulated.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 49 (6), 617-624,644, 2000

    公益社団法人 日本油化学会

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