Adsorption and Micelle Formation of Mixed Surfactant Systems in Water 2: A Combination of Cationic Gemini-type Surfactant with MEGA-10
-
- SUGIHARA Gohsuke
- Dept. Chem, Fac. Sci., Fukuoka University
-
- MIYAZONO Ayaki
- Dept. Chem, Fac. Sci., Fukuoka University
-
- NAGADOME Shigemi
- Dept. Chem, Fac. Sci., Fukuoka University
-
- OIDA Tatsuo
- Fac. Eng. & Design, Kyoto Institute of Technology
-
- HAYASHI Yoshiyuki
- Fac. Eng. & Design, Kyoto Institute of Technology
-
- KO Jeong-Soo
- Dept. Chem. Mokpo National University
書誌事項
- タイトル別名
-
- Adsorption and Micelle Formation of Mixed Surfactant Systems in Water II: A Combination of Cationic Gemini-type Surfactant with MEGA-10
この論文をさがす
抄録
Mixed micellization and mixed adsorbed film formation were investigated for the combination of a Gemini type cationic and a nonionic surfactants mixture: Bis-trimethyl ammonium Gemini derived from tartaric acid bromide (BAGTB) and n-Decanoyl-N-methylglucamide (MEGA-10). The surface tension of the aqueous mixed surfactant solution was measured at every 0.1 mole fraction of MEGA10 in the surfactant mixture applying a drop volume method at 30°C. From the curves of surface tension (γ) vs logarithmic concentration in molality (ln m ), critical micellization concentration (CMC), minimum surface tension at CMC (γCMC), surface excess (Γ), mean surface area occupied by a molecule (A m) and parameters related to synergism in surface activity such as pC20 and CMC / C20 were determined. Based on the regular solution theory, the relation of compositions of the singly dispersed phase (X MEGA10) and the micellar phase (Y MEGA10), and the relation of X MEGA10 with the composition in adsorbed film phase (Z 2) were estimated, and along with these, the interaction parameters in micelles (ωR) and in adsorbed film (ωA ) were calculated. Both the CMC-X MEGA-10 and CMC-Y MEGA-10 curves showed a negative deviation from ideal mixing and even the curve of Z MEGA10-m t (bulk phase concentration) produced a slightly negative ωA . However, the synergism in surface tension reduction was found to be rather weak from examination of partial molecular area (PMA) and the minimum free energy at surface G min(S) = (γCMC·A m·L ). As for the adsorbed film, the interaction mode between molecules, as well as two dimensional molecular packing, was observed to be separated into three regions; i. e. at X STDS = 0.45 and at X STDS = 0.75 different properties changed discontinuously.<br>
収録刊行物
-
- Journal of Oleo Science
-
Journal of Oleo Science 52 (9), 449-461, 2003
公益社団法人 日本油化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001204091051904
-
- NII論文ID
- 130000060585
-
- NII書誌ID
- AA11503337
-
- COI
- 1:CAS:528:DC%2BD3sXmvFyrsbk%3D
-
- ISSN
- 13473352
- 13458957
-
- NDL書誌ID
- 6648358
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可