Sodium-23 NMR Studies of Sodium Ion Ensembles with a 1,3-Alternate-Shaped Calix[4]arene
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- ARIMURA Takashi
- Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- NISHIOKA Takuya
- Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- KUMAMOTO Satoshi
- Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- TSUCHIYA Youichi
- Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- YAMAGUCHI Tomohiko
- Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- TACHIYA M.
- Fellow, National Institute of Advanced Industrial Science and Technology (AIST)
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Sodium-23 NMR longitudinal magnetization recovery (L.M.R.) study has been carried out to clarify the sodium ion exchange in ensembles with 1,3-alternate-shaped calix[4]arene 1 for the first time. The line width υ1/2 of a sharp singlet for NaClO4 in the absence of 1 is 65 Hz: upon addition of 1 a singlet peak was broadened to 1100 Hz (υ1/2). The life times (τ) of Na+ were estimated to be (20-3.8)×10-3 s for τA and (5.0-2.0)×10-3 s for τB, by the simulations of sodium-23 NMR L.M.R. curves. The life times of 1-Na+ Ensemble are larger than those for 18-crown-6. This implies that Na+ cation is bound deeply in the cavity formed by two OCH2CO groups of 1, the complex being classified as a “nest-in-type”.<br>
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 55 (2), 71-74, 2006
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204091388160
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- NII論文ID
- 130000055583
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- NII書誌ID
- AA11503337
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 7773637
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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