Heat Deterioration of Phospholipids(3)Thermally Deteriorated Products from Phosphatidylethanolamine and Hexose
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- HAMAGUCHI Nobutoshi
- Research and Development Section, Tsuji Oil Mill Co., Ltd.
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- KASAHARA Yoshihito
- Department of Bioresources Science, Faculty of Agriculture, Kochi University
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- HAYASHI Akihito
- Research and Development Section, Tsuji Oil Mill Co., Ltd.
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- SONO Ryoji
- Research and Development Section, Tsuji Oil Mill Co., Ltd.
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- TEBAYASHI Shin-ichi
- Department of Bioresources Science, Faculty of Agriculture, Kochi University
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- KIM Chul-Sa
- Department of Bioresources Science, Faculty of Agriculture, Kochi University
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- KOH Hen-Sik
- Research and Development Section, Tsuji Oil Mill Co., Ltd.
書誌事項
- タイトル別名
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- Heat Deterioration of Phospholipids. III. Thermally Deteriorated Products from Phosphatidylethanolamine and Hexose
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抄録
Novel four 2,3-dihydro-1H-imidazo[1,2-a]pyridine-4-ylium derivatives were obtained with increase of UV absorption at 350 nm and browning of the solution by heating paste lecithin from soybean (SL) in octane. These four derivatives were characterized the factor based on UV absorption at 350 nm. The SL was separated into the hexane (DSSL fr.) and 60% ethanol in water frs. by liquid- liquid partition method. Even when the DSSL fr. was heated in octane more than 9 h, the four derivatives were not formed and increase of any UV absorption was also not observed but the solution color was slightly yellowing. On the other hand, the formation of four derivatives and increase of UV absorption at 350 nm were observed when DSSL and 60% ethanol in water frs. were combined and, then, heated in octane. From the 60% ethanol in water fr, sucrose, raffinose and stachyose were isolated and identified as compounds which involved the formation of the derivatives with the DSSL fr. When DSPE (1,2-di-O-stearoyl-sn-glycero-3-phosphatidylethanolamine) and any hexose were combined and then heated, two 2,3-dihydro-1H-imidazo[1,2-a]pyridine-4-ylium derivatives generated with increase of UV absorption at 350 nm and browning. From these results, it is concluded that the formation of derivatives, with increase of the UV absorption at 350 nm and browning, are based on the reaction of sugars and phosphatidylethanolamine (PE) in SL.<br>
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 55 (10), 503-509, 2006
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204093257088
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- NII論文ID
- 130000055601
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- NII書誌ID
- AA11503337
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 8052089
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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