Bright Silver Plating from Cyanide-Free Bath.
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- MASAKI Seishi
- Daiwa Fine Chemicals Co., Ltd.
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- INOUE Hiroyuki
- College of Eng., Osaka Pref. Univ.
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- YAMAKAWA Koji
- College of Eng., Osaka Pref. Univ.
Bibliographic Information
- Other Title
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- 非シアン浴からの光沢銀めっき
- ヒ シアンヨク カラ ノ コウタク ギン メッキ
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Abstract
Bright silver coatings were obtained from silver-succinimide baths. The pH dependence on the rest potential of Ag electrodes and the cathodic polarization curve were measured to clarify the electrodeposition mechanism. The effects of pH, temperature, and the bath's silver concentration on surface appearance were evaluated using Hull Cell tests. The current efficiency and microscopic surface morphology were also examined.<br>The bath composition and operating conditions most conductive to obtaining a mirror-bright surface on the electroplated silver were 0.45mol/L of CH3SO3Ag, 1.5mol/L of succinimide, 0.025mol/L of Na2B4O7, a pH of 10, and a 25°C bath temperature. Cathode current efficiency exceeded 90% at current densities between 10 and 20mA/cm2. It was estimated that the silver was deposited from Ag (C4H4O2N)2- complex ion and the process was controlled by the charge transfer in the bath.
Journal
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- Journal of The Surface Finishing Society of Japan
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Journal of The Surface Finishing Society of Japan 48 (5), 559-564, 1997
The Surface Finishing Society of Japan
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Details 詳細情報について
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- CRID
- 1390001204114528128
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- NII Article ID
- 10002259142
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- NII Book ID
- AN1005202X
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- ISSN
- 18843409
- 09151869
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- NDL BIB ID
- 4217065
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed