Glycosylation Using 2-Azido-3,4,6-tri-<i>O</i>-benzyl-2-deoxy-<scp>d</scp>-glucose, -galactose, and -mannose with the Aid of <i>p</i>-Nitrobenzenesulfonyl Chloride–Silver Trifluoromethanesulfonate–Triethylamine System
-
- Koto Shinkiti
- School of Pharmaceutical Sciences, Kitasato University
-
- Asami Kazuyasu
- School of Pharmaceutical Sciences, Kitasato University
-
- Hirooka Motoko
- School of Pharmaceutical Sciences, Kitasato University
-
- Nagura Kazuo
- School of Pharmaceutical Sciences, Kitasato University
-
- Takizawa Mizue
- School of Pharmaceutical Sciences, Kitasato University
-
- Yamamoto Satoko
- School of Pharmaceutical Sciences, Kitasato University
-
- Okamoto Nami
- School of Pharmaceutical Sciences, Kitasato University
-
- Sato Mitsuko
- School of Pharmaceutical Sciences, Kitasato University
-
- Tajima Hiromi
- School of Pharmaceutical Sciences, Kitasato University
-
- Yoshida Toyosaku
- School of Pharmaceutical Sciences, Kitasato University
-
- Nonaka Nobuo
- School of Pharmaceutical Sciences, Kitasato University
-
- Sato Tadaaki
- School of Pharmaceutical Sciences, Kitasato University
-
- Zen Shonosuke
- School of Pharmaceutical Sciences, Kitasato University
-
- Yago Kazuo
- Department of Pharmacy, Kitasato University Hospital
-
- Tomonaga Fumiya
- Department of Pharmacy, Kitasato University Hospital
書誌事項
- タイトル別名
-
- Glycosylation Using 2-Azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucose, -galactose, and -mannose with the Aid of p-Nitrobenzenesulfonyl Chloride-Silver Trifluoromethanesulfonate-Triethylamine System.
抄録
This report describes a simple synthesis of 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranose. Glycosylation using this as well as 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-galactopyranose and -mannopyranose was achieved with the aid of a reagent system consisting of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, and its modifications. O-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-(1→4)-O-α-D-mannopyranosyl-(1→4)-α-D-mannopyranose, the repeating unit of the main chain of the O-specific cell wall polysaccharide of E. coli 058 was synthesized.
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 72 (4), 765-777, 1999
公益社団法人 日本化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001204119822976
-
- NII論文ID
- 130004150337
-
- ISSN
- 13480634
- 00092673
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可