Dynamics of Molecules and Clusters Studied by Low-Temperature Matrix-Isolation Infrared Spectroscopy and Density-Functional-Theory Calculations.
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- Nakata Munetaka
- Graduate School of BASE (Bio-Applications and Systems Engineering), Tokyo University of Agriculture and Technology
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Abstract
This article presents an account of applications of low-temperature matrix-isolation (MI) infrared spectroscopy combined with density-functional-theory (DFT) calculations to studies of dynamics of molecules and clusters. The MI technique using a conventional Fourier transform infrared (FTIR) spectrophotometer can measure infrared spectra of less stable isomers, clusters produced by photolysis or supersonic-jet expansion, electronically excited species, and unstable radicals. The observed wavenumbers are compared with the calculated values obtained by the DFT calculation and are used for accurate identification of the structures, including conformations around some rotational axes. Thus photoreaction mechanisms of molecules and clusters are elucidated.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 75 (6), 1173-1189, 2002
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001204121787264
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- NII Article ID
- 130004058455
- 10010672815
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- NII Book ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL BIB ID
- 6188644
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed