A New Way for Efficient Catalysis by Using Low Valent Ruthenium Complexes as Redox Lewis Acid and Base Catalysts.
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- Murahashi Shun-Ichi
- Department of Chemistry, Faculty of Engineering Science, Osaka University
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- Naota Takeshi
- Department of Chemistry, Faculty of Engineering Science, Osaka University
書誌事項
- タイトル別名
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- New Way for Efficient Catalysis by Usin
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Low valent ruthenium hydride complexes are excellent catalysts which act as either redox Lewis acid or base catalysts. Nitriles are substrates which have strong coordination ability towards transition metals, so new types of catalytic transformations of nitriles have been explored using these catalysts. As redox Lewis acid catalysts, hydration of nitriles, amidation of amines, and esterification of alcohols with nitriles can be achieved. The same catalyst can be used for direct formation of carbon nucleophiles by C–H activation of pronucleophiles, such as nitriles and carbonyl compounds, hence catalytic aldol-type reactions and Michael-type additions can be performed under neutral and mild conditions.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 69 (7), 1805-1824, 1996
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204122497024
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- NII論文ID
- 130004149602
- 10008905110
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL書誌ID
- 4060436
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可