Cobalt(III) Complexes with Quadridentate Ligands. XIII. The Preparation and Properties of <i>cis</i>-<i>α</i>, <i>cis</i>-<i>β</i>1, and <i>cis</i>-<i>β</i>2-Isomers ofthe (2-Oxidephenylacetato)(triethylenetetramine)cobalt(III) Complex

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  • Sekizaki Haruo
    Faculty of Pharmaceutical Sciences, Higashi Nippon Gakuen University
  • Chinen Chisako
    Faculty of Pharmaceutical Sciences, Higashi Nippon Gakuen University
  • Toyota Eiko
    Faculty of Pharmaceutical Sciences, Higashi Nippon Gakuen University
  • Yamamoto Yoshihisa
    Faculty of Pharmaceutical Sciences, Higashi Nippon Gakuen University

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タイトル別名
  • Cobalt(III) Complexes with Quadridentate Ligands. XIII. The Preparation and Properties of cis-.ALPHA., cis-.BETA.1, and cis .BETA.2-Isomers of the (2-Oxidephenylacetato)(triethylenetetramine)cobalt(III) Complex.

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説明

The cis-α, cis-β1, and cis-β2-isomers of (2-oxidephenylacetato)(triethylenetetramine)cobalt(III) chloride hydrate, [Co(opa)(trien)]Cl·nH2O (opa = 2–oxidephenylacetato, trien = triethylenetetramine), have been prepared and characterized by means of analytical and spectroscopic methods. The cis-α and cis-β1-isomers of this complex were more stable than those of the salicylato- or thiosalicylato(triethylenetetramine)cobalt(III) complexes in basic aqueous solution.

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