Sodium sulfate mixed with rare earth sulfates(Ln=Y and Gd) and silicon dioxide as a solid electrolyte for a sulfur dioxide detector.
-
- Imanaka Nobuhito
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
-
- Yamaguchi Yasuo
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
-
- Adachi Gin-ya
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
-
- Shiokawa Jiro
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
抄録
Sodium sulfate mixed with rare earth sulfates(Ln=Y and Gd) and silicon dioxide exhibits a Na2SO4-I-like phase as well as a small amount of silicon dioxide phase. The former phase is excellent in Na+ ion conduction. The electrical conductivity of the Na2SO4–Ln2(SO4)3–SiO2(Ln=Y and Gd) systems is considerably higher than that of pure sodium sulfate. When the Na2SO4–Ln2(SO4)3–SiO2(Ln=Y and Gd) sample is applied as a solid electrolyte for a SO2 gas concentration cell, the measured EMF is in good agreement with the calculated EMF for a SO2 gas concentration range from 0.1% (1000 ppm) to 23%, and 0.32% (3200 ppm) to 10%, respectively.
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 58 (1), 5-8, 1985
公益社団法人 日本化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001204123670400
-
- NII論文ID
- 130001984272
-
- ISSN
- 13480634
- 00092673
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可