Sodium sulfate doped with sodium vanadate and rare earth sulfate as a solid electrolyte for a sulfur dioxide gas detector.
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- Imanaka Nobuhito
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Adachi Gin-ya
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Shiokawa Jiro
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
Abstract
Sodium sulfate doped with NaVO3 and Ln2(SO4)3 (Ln=Eu, Pr, and Y) show higher electrical conductivity for Na+ ions and maintains a high temperature phase, Na2SO4–I, without showing phase transformation. The electromotive force (EMF) using solid solutions, Na2SO4–NaVO3–Ln2(SO4)3 (Ln=Pr and Y), as solid electrolytes exhibits good agreement with the calculated value, the temperature as low as 673 K which is approximately 300 K lower than pure sodium sulfate can be.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 57 (3), 687-691, 1984
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001204125152512
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- NII Article ID
- 130001984565
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- ISSN
- 13480634
- 00092673
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed