Total synthesis of furanoeremophilane and 14-norfuranoeudesmane derivatives by a route involving alkylation of 2,4-dimethyl-3-furoic acid.

  • Tada Masahiro
    Tokyo University of Agriculture and Technology, Laboratory of Bioorganic Chemistry
  • Sugimoto Yayoi
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Takahashi Takeyoshi
    Department of Chemistry, Faculty of Science, The University of Tokyo

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説明

(±)-14-Norfuranoeudesmane-4,6-dione, (±)-furanoeremophilane-3,6-dione, and (±)-furanoeremophilan-14, 6α-olide were synthesized by a route involving alkylation of a dianion obtained from 2,4-dimethyl-3-furoic acid.

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