The Backbone Rearrangement of 3β,4β-Epoxyfriedelane and the Synthesis of Dendropanoxide

DOI DOI PDF 被引用文献11件 参考文献14件 オープンアクセス
  • Tori Motoo
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Torii Takahiro
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Tachibana Kazuo
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Yamada Sachiko
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Tsuyuki Takahiko
    Department of Chemistry, Faculty of Science, The University of Tokyo
  • Takahashi Takeyoshi
    Department of Chemistry, Faculty of Science, The University of Tokyo

書誌事項

タイトル別名
  • The backbone rearrangement of 3.BETA.,4.BETA.-epoxyfriedelane and the synthesis of dendropanoxide.
  • ChemInform Abstract: THE BACKBONE REARRANGEMENT OF 3β,4β‐EPOXYFRIEDELANE AND THE SYNTHESIS OF DENDROPANOXIDE

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説明

Dendropanoxide (1) was synthesized by the reaction of 3β,4β-epoxyfriedelane (19) with boron trifluoride etherate in ether at −10 °C. In the rearrangement reaction, 4α-fluorofriedelan-3β-ol (20), D : B-friedo-olean-5(10)-en-3β-ol (21), β-amyrin (22), and D : B-friedo-olean-5-en-3β-ol (23) were also produced.

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