Award Accounts : The Chemical Society of Japan Award for Young Chemists for 2008 : Designs of Functional π-Electron Materials based on the Characteristic Features of Boron
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- Wakamiya Atsushi
- Institute for Chemical Research, Kyoto University
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- Yamaguchi Shigehiro
- Department of Chemistry, Graduate School of Science, and Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
書誌事項
- タイトル別名
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- Designs of Functional π-Electron Materials based on the Characteristic Features of Boron
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抄録
Boron, a group 13 element, has several characteristic structural and electronic features: 1) trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence of a vacant p-orbital, effective orbital interaction with π-conjugated compounds is possible; 3) the presence of a vacant p-orbital is furthermore responsible for high Lewis acidity; 4) the boryl group acts as a π-electron-accepting group particularly in the excited state. The consequent exploitation of these characteristic features of boron in the molecular design enables us to produce sophisticated π-functional materials with attractive photophysical and electronic properties. This account article illustrates our systematic studies on the molecular design and the development of functional π-electron materials using boron as a key element.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 88 (10), 1357-1377, 2015
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204141355648
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- NII論文ID
- 130005102813
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL書誌ID
- 026791125
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可