Photoinduced Large Increase in the Refractive Index of <i>N</i>-2-Thenoyloxyaryl-4-<i>tert</i>-butylphenoxyacetamide Film

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  • Arai Taichi
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University
  • Kobayashi Sakiho
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University
  • Oshimi Natsuko
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University
  • Igarashi Tetsutaro
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University
  • Sakurai Tadamitsu
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University

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  • Photoinduced Large Increase in the Refractive Index of N-2-Thenoyloxyaryl-4-tert-butylphenoxyacetamide Film

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The irradiation of N-2-thenoyloxyaryl-4-tert-butylphenoxyacetamides in their molecular film states at 254 nm was found to selectively afford the corresponding photo-Fries rearranged products. This rearrangement reaction was also found to lead to a large increase in the refractive indices of the films, which ranged from 0.021 to 0.035.

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