Stereoselective Synthesis of Lurlenic Acid and Lurlenol, the Sex Pheromones of the Green Flagellate Chlamydomonas.

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  • MORI Kenji
    Department of Chemistry, Faculty of Science, Science University of Tokyo
  • TAKANASHI Shin-ichi
    Department of Chemistry, Faculty of Science, Science University of Tokyo

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  • Stereoselective Synthesis of Lurlenic A

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Abstract

Lurlenicacid[(4E, 8E, 12E)-14-[2'-hydroxy-3', 4'-dimethyl-5'-(1"-β-D-xylopyranosyloxy) phenyl]-4, 8, 12-trimethyltetradeca-4, 8, 12-trienoic acid, 1] and lurlenol (2), the sex pheromones produced by the female gametes of the green flagellate Chlamydomonas, were synthesized stereoselectively.

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