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New Cyclic Depsipeptide Antibiotics, Clavariopsins A and B, Produced by an Aquatic Hyphomycetes, Clavariopsis aquatica.
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- SUZUKI YOSHIHIRO
- Graduate School of Bioagricurtural Sciences, Nagoya University
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- OJIKA MAKOTO
- Graduate School of Bioagricurtural Sciences, Nagoya University
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- SAKAGAMI YOUJI
- Graduate School of Bioagricurtural Sciences, Nagoya University
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- KAIDA KENICHI
- Pharmaceutical Research Laboratories, Ajinomoto Co., Inc.
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- FUDOU RYOSUKE
- Central Research Laboratories, Ajinomoto Co., Inc.
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- KAMEYAMA TOSHIYUKI
- Pharmaceutical Research Laboratories, Ajinomoto Co., Inc.
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Description
The structures of new cyclic decadepsipeptides, clavariopsins A and B, were determined to be cyclo[-(R)-2-hydroxyisovaleryl-L-pipecolyl-L-MeVal-L-Val-L-MeAsp-L-Mene-L-Melle-Gly-L-MeVal-L-Tyr(OMe)-] and cyclo[-(R)-2-hydroxyisovaleryl-L-pipecolyl-L-Val-L-Val-L-MeAsp-L-Melle-L-Melle-Gly-L-MeVal-L-Tyr(OMe)-], respectively, by spectroscopic analyses, especially using 2D NMR techniques. The absolute stereochemistry was elucidated by the advanced MARFEY'S method and chiral HPLC analysis.
Journal
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- The Journal of Antibiotics
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The Journal of Antibiotics 54 (1), 22-28, 2001
JAPAN ANTIBIOTICS RESEARCH ASSOCIATION
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Keywords
Details 詳細情報について
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- CRID
- 1390001204149048960
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- NII Article ID
- 130003503806
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- COI
- 1:CAS:528:DC%2BD3MXhvVCitbY%3D
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- ISSN
- 18811469
- 00218820
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- PubMed
- 11269711
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- JaLC
- Crossref
- PubMed
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed