ChemInform Abstract: Diels—Alder Reaction of 1,2,3‐Benzotriazine with Enamine: Application to the Synthesis of Alkaloids, 2‐Propylquinoline and 2‐Pentylquinoline.

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  • Diels-Alder Reaction of 1,2,3-Benzotriazine with Enamine: Application to the Synthesis of Alkaloids, 2-Propylquinoline and 2-Pentylquinoline.
  • Diels Alder Reaction of 1 2 3 Benzotria

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説明

The Diels-Alder reaction of 1, 2, 3-benzotriazine with several pyrrolidine enamines of carbonyl compounds was carried out in chloroform in the presence of zinc bromide to afford 2- or 3-mono-, or 2, 3-disubstituted quinolines. This method was applied to the synthesis of the alkaloids, 2-propylquinoline and 2-pentylquinoline.

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