Synthesis of Four Possible Intermediates after Secologanin on the Biosynthesis of the Oleoside-, 10-Hydroxyoleoside- and Ligustaloside-Type Glucosides in Oleaceous Plants.

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  • Synthesis of Four Possible Intermediate

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To examine the biosynthetic pathway from secologanin to three types of secoiridoid glucosides characteristic of oleaceous plants, synthesis of two respective stereoisomers at C-8 of 8, 10-epoxysecologanin and -secoxyloganin was established and their deuterium-labeled analogues were prepared.

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